Stokes-Einstein Equation:
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The diffusion constant (D) quantifies how quickly particles diffuse through a medium at a given temperature. It's a fundamental parameter in understanding Brownian motion and transport phenomena in physics, chemistry, and biology.
The calculator uses the Stokes-Einstein equation:
Where:
Explanation: The equation relates the diffusion constant to temperature, viscosity, and particle size, showing that smaller particles diffuse faster in less viscous media at higher temperatures.
Details: The diffusion constant is crucial for understanding processes like chemical reactions, biological transport, material science, and environmental processes. It helps predict how quickly molecules will spread in a given medium.
Tips: Enter temperature in Kelvin, viscosity in Pascal-seconds (Pa·s), and particle radius in meters. All values must be positive numbers.
Q1: What are typical values for diffusion constants?
A: In water at room temperature, small molecules have D ≈ 10⁻⁹ m²/s, while larger molecules like proteins have D ≈ 10⁻¹¹ m²/s.
Q2: What are the limitations of the Stokes-Einstein equation?
A: It assumes spherical particles, continuum fluid, no particle-particle interactions, and no-slip boundary conditions.
Q3: How does temperature affect diffusion?
A: Diffusion increases with temperature (D ∝ T) as higher thermal energy drives more vigorous particle motion.
Q4: What's the difference between D and the diffusion rate?
A: D is a material property, while diffusion rate depends on D and the concentration gradient (Fick's first law).
Q5: Can this be used for gases?
A: The equation is primarily for liquids. Gas diffusion is better described by kinetic theory equations.