Boiling Point Elevation Equation:
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Boiling point elevation (ΔTb) is the phenomenon where the boiling point of a liquid increases when another compound is added, meaning a solution has a higher boiling point than the pure solvent. This is a colligative property that depends on the number of solute particles in the solution.
The calculator uses the boiling point elevation equation:
Where:
Explanation: The equation shows that boiling point elevation is directly proportional to the molality of the solute and the number of particles it dissociates into in solution.
Details: Calculating boiling point elevation is important for determining solution properties, designing industrial processes, and understanding biological systems where solute concentrations affect boiling points.
Tips: Enter the solvent's Kb value, solution molality, and Van't Hoff factor. Common Kb values: water (0.512), benzene (2.53), ethanol (1.22) °C·kg/mol.
Q1: Why does boiling point elevation occur?
A: It occurs because solute particles lower the solvent's vapor pressure, requiring higher temperature to reach atmospheric pressure for boiling.
Q2: What's the difference between Kb and Kf?
A: Kb is for boiling point elevation while Kf is for freezing point depression. Both are solvent-specific constants.
Q3: How does the Van't Hoff factor affect ΔTb?
A: The factor accounts for solute dissociation. For NaCl, i≈2 (dissociates into Na+ and Cl-); for glucose, i=1 (doesn't dissociate).
Q4: Can this calculator compare multiple solutions?
A: Currently it calculates for one solution at a time. For comparisons, calculate each separately and compare the ΔTb values.
Q5: What are limitations of this calculation?
A: It works best for dilute solutions. For concentrated solutions or strong electrolytes, deviations may occur due to interparticle interactions.